What Causes Air
Pollution?
Areas of India and Bangladesh have air that is so polluted it harms people’s health.
When harmful substances build up in the air to unhealthy levels, the result i s air p olluti on.
A volcano, for example, can spew clouds of particles and sulfur dioxide, SO 2 Natural pollutants also include dust, pollen, and spores.
Primary and Secondary Pollutants
A pollutant that is put directly into the air by human activity is called a prim ary polluta nt . An example of a primary pollutant is soot from smoke. Figure 1.1 shows some sources of primary air pollutants. Second ary poll ut- an ts f orm when primary pollutants react with other primary pollutants or Ground-level ozone forms when the ultraviolet rays of the sun cause emissions from cars, trucks, and other sources to react with oxygen in the atmosphere.
FIGURE 1.1
Primary Air Pollutants Each day in the United States, hundreds of thousands of tons of polluting emissions that result from human activity enter the air.
SECTION 1
Objectives
ame five primary air ollutants and give sources
for each.
ame the two major sources of ir pollution in urban areas.
escribe the way in which mog forms.
xplain the way in which a thermal inversion traps air pollution.
Key Terms air pollution
primary pollutant secondary pollutant smog
temperature inversion
CHECK FOR UNDERSTANDING
Explain How is ground-level ozone an example of a secondary pollutant?
SECTION
1
Focus and Motivate
Objectives
Pollution from automo-biles and industry is discussed, along with smog and temperature inversions.
Classroom Catalyst
Divide the class into small groups, and tell them to use humor, as Cohen did, to complete the following sentence: “You know the air is polluted when…”
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Sources of Primary Air Pollutants in the U.S. (Per Day) |
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tons) |
70 |
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Carbon monoxide (CO) |
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60 |
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Nitrogen oxides (NOx) |
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of |
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Particulate matter (PM) |
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(inthousands |
50 |
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Sulfur oxides (SOx) |
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Volatile organic compounds (VOCs) |
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40 |
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Emissions |
30 |
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20 |
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10 |
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0 |
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Electricity production |
Industry |
Transportation |
Other sources |
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Source: U.S. Environmental Protection Agency.
Differentiated Instruction |
Chapter 12: Air303 |
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INCLUSION
Have students use a word processor, pencil and paper, or posterboard to list the sources of primary air pollutants in Figure 1.1 Have students estimate how much pollution is produced by each source of primary air pollution.
Classroom Discussion
Comparing Cigarette Smoke and Pollution Poll the class, and ask how Ask, “If cigarette manufacturers are being held accountable for the health effects of the use of their products, should industries be accountable for the effects of the pollutants they discharge into the air?”
Answers
Check for Understanding
Ground-level ozone is a secondary pollutant because it forms when primary pollutants react with oxygen in the presence of UV radiation.
Chapter 12: Air 303
Teach
Misconception Alert!
Invisible Pollutants Many people Have students compile their results in a table that lists the acceptable amounts allowed in the air, the levels in your community, and the health problems associated with each pollutant.
FIGURE 1.2
Pollutant
Carbon monoxide (CO)
Nitrogen oxides (NO x )
Sulfur dioxide (SO 2 )
Volatile organic compounds (VOCs)
Particulate matter (particulates or„PM)
PRIMARY AIR POLLUTANTS
Description |
Primary Sources |
Effects |
CO is an odorless, colorless, |
Sources of CO are cars, |
CO interferes with the blood’s ability |
It is |
trucks, buses, small |
to carry oxygen, slowing reflexes |
produced by the incomplete |
engines, and some industrial |
In high |
burning of fossil fuels. |
processes. |
concentrations, CO can cause death. |
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When combustion (burning) |
NO x comes from burning fuels |
NO x can make the body vulnerable to |
temperatures exceed |
in vehicles, power plants, and |
respiratory infections, lung diseases, |
538°C, nitrogen and |
industrial boilers. |
NO x contributes to the |
oxygen combine to form |
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brownish haze seen over cities and to |
nitrogen„oxides. |
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acid„precipitation. |
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SO 2 is produced by |
SO 2 comes mostly from |
SO 2 contributes to acid precipitation as |
chemical interactions |
burning fossil fuels. |
Secondary pollutants that |
between sulfur and oxygen. |
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result from reactions with SO 2 can harm |
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plant life and irritate the respiratory |
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systems of humans. |
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VOCs are organic chemicals |
VOCs come from burning |
VOCs contribute to smog formation and |
that vaporize readily and |
Vehicles are a major |
can cause serious health problems, such |
form toxic fumes. |
source of VOCs. |
They may also harm plants. |
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Particulates are tiny |
Most particulates come from |
Particulates can form clouds that |
particles of liquid or |
construction, agriculture, |
reduce visibility and cause a variety of |
solid„matter. |
Vehicles |
Particulates have |
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and industrial processes also |
As well, they |
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contribute particulates. |
may corrode metals and erode buildings |
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and„sculptures. |
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Differentiated Instruction
Connect to LAW
Off with His Head!
Around 1300 CE “Be it known to all within the sound of my voice,” King Edward I said, “whosoever shall be found burning coal shall suffer the loss of his head.”
304 Unit 4: Water, Air, and Land
Sources of Primary Air Pollutants
As shown in Figure 1.2 above, household products, power plants, and motor vehicles are sources of primary air pollutants such as carbon monoxide, nitrogen oxide, sulfur dioxide, and chemicals called volatile organic compounds Carbon monoxide gas is an important VOCs are also found in many household products.
Sources of coarse particles are cement plants, mining operations, incinerators, wood-burning fireplaces, fields, and roads.
inclusion
Paired Summarizing Have each student pair with a partner and take turns reading and summarizing the primary pollutants identified in Figure 1.2 Student pairs should also offer two examples of each category of primary pollutant.
Group Activity
Collecting Particulate Matter Check the air Students should also
As an extension, try this experiment at different times of the year and in different locations in your community.
304 Unit 4: Water, Air, and Land
The History of Air Pollution
One man was even executed for disobey-ing this medieval “clean air act.”
As represented in Figure 1.3 , most air pollution in industrialized countries comes from mo-tor vehicles and industry.
ECO FACT
Sea-Coal
The smoke emanated from London homes and factories and combined with fog to produce smog.
Global Awareness
Looking to Latin America Enrique To get to work or school, everyone
Motor Vehicle Emissions
The rest was from trucks and‹buses.
FIGURE 1.3
Sources of Air Pollution The refinery shown in this photograph is a The truck in the foreground is emitting nitrous oxide into the atmosphere.
would ride public transportation or bicycles, or they would walk.
Make It Relevant
Local Air Quality Air quality varies Have students
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Controlling Vehicle Emissions |
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The Clean Air Act, passed in 1970 and |
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strengthened in 1990, gives the Envi- |
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ronmental Protection Agency (EPA) the |
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authority to regulate vehicle emissions |
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The EPA required |
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the gradual elimination of lead in gaso- |
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line, and as a result, lead pollution has |
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been reduced by more than 90 percent in |
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In addition, catalytic |
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converters, which are required in auto- |
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mobiles, clean exhaust gases of pollutants |
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before the pollutants are able to exit the |
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The EPA indicates that light-duty |
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cars and trucks in 2010 burned fuel ap- |
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proximately 70 percent more efficiently |
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and with about 40‹percent fewer emis- |
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sions of carbon dioxide than they did in |
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In addition, cars and trucks produce |
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Images |
approximately 95 percent fewer emissions |
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of pollutants other than carbon dioxide |
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©A.T.Willett/Alamy |
than they did in the 1970s. |
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Chapter 12: Air |
305 |
What are the weather conditions that lead to the worst and best air quality in your area?”
Connect to History
“Valley of the Smokes” Centuries ago, Native Americans knew the Los Angeles Basin as the “Valley of the Smokes” because frequent temperature inversions trapped the smoke from their fires, casting a gray pall over the valley.
Group Activity
Reducing Auto Emissions In the 1970s, Honda What improvements are planned to meet the tougher emission standards of the future?”
Students may mention electric cars, hybrid cars, dual fuel systems that permit a car to use either natural gas or gasoline, and solar cars.
Chapter 12: Air 305
Teach continued
Homework
Evaluating Car Use Tell students to Are there any trips that might make
Connect to MATH
Utility Incentives for Zero-emission Vehicles
How much would you save if you had three electric cars?
California Zero-Emission Vehicle Program
A catalytic converter, as shown in Figure 1.4 ZEV programs have also been adopted in Maine, Massachusetts, New York, and Vermont.
Zero-emission vehicles have no tailpipe emissions, no emissions from One type is clean, fuel-efficient hybrid cars, which are powered by both batteries and gasoline engines.
As of 2011, such hydrogen-powered ve-hicles are still mostly in the prototype stage of development.
Suggest that students include their responses in their science journal.
EcoSmart
FIGURE 1.4
Car Emission The catalyst material in a catalytic converter (top) speeds up a chemical reaction that changes exhaust The text below the images shows a car’s contribution to air pollution.
Allowance Trading System The EPA’s In this system, 1 ton of sulfur dioxide (SO 2 Sulfur dioxide allow-ances are inexpensive and can be bought
Interior
• Car seats may be covered in plastic that contains a volatile organic compound called vinyl chloride .
Body and Frame
• Steel smelters send thousands of metric tons of sulfur dioxide into the air each year.
• Many auto factories in Mexico, Eastern Europe, and some Asian countries lack pollution-control devices.
Fuel Tank
• When filling the car with gasoline, VOCs escape†into†the†atmosphere.
Exhaust
• Car exhaust is a major source of nitrogen oxides, carbon monoxide, and hydrocarbons.
• In developing countries, car exhaust may contain over a thousand poisonous substances.
Purchasing one allowance will reduce a company’s allowable SO 2 emissions in a given year by 1 ton.
Answers
Connect to Math
$0.025 × 150 hours = $3.75/month $3.75 × 12 months = $45.00 $45.00 × 3 vehicles = $135.00/year
306 Unit 4: Water, Air, and Land
Differentiated Instruction
pre-ap
The Yellow Bikes Program In an effort to The idea is that a resident
Have students investigate the possibility of instituting a “Yellow Bikes” program in their area.
FIGURE 1.5
Industrial Pollution In 1996, the federal government established standards to reduce emissions of VOC-producing chemicals used in dry cleaning.
Industrial Air Pollution
Power plants that produce electricity emit at least two-thirds of all sulfur dioxide and more than one-third of all nitrogen oxides that pollute the air.
Some industries, such as the dry cleaning industry shown in Figure 1.5 Oil refineries, chemical manufacturing plants, furniture refinishers, and automobile repair shops also contribute to the VOCs in the air.
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Regulating Air Pollution from Industry |
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The Clean Air Act requires many industries to use scrubbers or other |
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Scrubbers remove some of the more harmful |
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A scrubber , as shown |
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in Figure 1.6 , is a machine that moves gases through a spray of water that |
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dissolves many pollutants. |
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Electrostatic precipitators are machines used in cement factories and |
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In |
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an electrostatic precipitator, gas containing dust particles is blown through |
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Newman/PhotoEdit |
An electrical charge is transferred to the dust particles, |
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Electrostatic precipitators |
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which causes them to stick to one another and the sides of the chamber. |
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©Michael |
The clean gas is released from the chamber, and the concentrated dust |
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plants from the air each year in the United States. |
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remove more than 20 million tons of ash generated by coal-burning power |
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Group Activity
Air Pollution and the Individual Divide the At what point would the level of air pollutants in the air be high enough for me to take action?”
ECO
FACT
Air Pollution’s Impact on Birds
The two species of birds respond differently
One
When heavy metal
emissions from the smelter decreased, a rapid improvement in breeding
success and a decrease in the heavy metal found in the bones of nestlings was observed.
FIGURE 1.6
Scrubber Scrubbers work by spraying gases with water, which removes many pollutants.
CHECK FOR UNDERSTANDING
Describe Name two pollution-control State how they help to limit the amount of pollutants in air.
Chapter 12: Air |
307 |
Demonstration
Temperature Inversion Fill the bottom Ask students to observe what happens. (The smoke Thus, the smoke is trapped below with the cooler air just as air pollutants are trapped in an urban environment.) Point These conditions include cloud cover, which reduces warming at the Earth’s surface, and lack of wind.
Connect to Geology
Vog and Laze Vog is volcanic smog that Physical and chemical interactions create white plumes of hydrochloric acid and concentrated salt water.
Answers
Check for Understanding
An electrostatic precipitator reduces pollution by removing dust particles from smokestacks.
Chapter 12: Air 307
Assess and Reteach
Quiz
Alternative
Assessment
Smog and Ozone Alerts Ask students They should also include advice about how people can minimize their exposure during the alert and about what individuals can do to help alleviate the problem.
Reteach
FIGURE 1.7
Smog The diagram below shows Large cities with dry, sunny climates and millions of automobiles often suffer from smog.
FIGURE 1.8
Air Circulation Normal air A temperature inversion, in which pollutants are trapped near Earth’s surface, is shown at right.
Smog
When air pollution hangs over urban areas and reduces visibility, it is calle d sm og As you can see in Figure 1.7 , smog results from chemical reactions that involve sunlight, air, automobile exhaust, and ozone.
Pollutants released by vehicles and industries are the main causes of smog.
Temperature Inversions
The warm air rises through the cooler air above and carries pollutants away from the ground and into the atmo-sphere.
Usually, air temperatures decrease with altitude, but sometimes a temperatu re i nversi on o ccurs when the air above is warmer than the air below. Figure 1.8 Los Angeles, which is surrounded on three sides by mountains, often has temperature inversions that trap smog in the city.
Pollution Sources Write the following pollution sources on the board:
Section 1
Formative Assessment
Finally, discuss the types
of pollutants that each source usually emits and possible remedies for those pollutants.
Reviewing Main Ideas
Critical Thinking
Answers to Formative Assessment
308 Unit 4: Water, Air, and Land
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